Chirality-Induced Catalyst Aggregation: Insights into Catalyst Speciation and Activity Using Chiral Aluminum Catalysts in Cyclic Ester Ring-Opening Polymerization

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چکیده

A series of chiral-at-metal aluminum complexes have been synthesized using chiral catam ligands. Reactivity studies demonstrate the importance alkoxide bulkiness and complex chirality in inducin...

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ژورنال

عنوان ژورنال: ACS Catalysis

سال: 2021

ISSN: ['2155-5435']

DOI: https://doi.org/10.1021/acscatal.0c05245